Search results for "Clay minerals"
showing 10 items of 77 documents
Geochemical insights into the relationship of rock varnish and adjacent mineral dust fractions
2020
Abstract Rock varnishes are μm-thin, dark, manganese(Mn)-rich crusts that accrete in the order of few μm/ka on weathering-resistant lithologies. Although these crusts can form in all climates, they are best known in arid to semi-arid settings. Aeolian dust is understood as a major contributor to the distinct trace metal and REE enrichments in rock varnish. However, the exact proportions of abiotic and biotic formation mechanisms that may explain the oxidation-reactions of Mn2+ to Mn4+, present as Mn oxyhydroxides in the varnish, are still a matter of ongoing debate. We present here the first systematic study of trace element enrichment processes between the uppermost layer of the varnish se…
Quantitative models of hydrothermal fluid–mineral reaction: The Ischia case
2013
Abstract The intricate pathways of fluid–mineral reactions occurring underneath active hydrothermal systems are explored in this study by applying reaction path modelling to the Ischia case study. Ischia Island, in Southern Italy, hosts a well-developed and structurally complex hydrothermal system which, because of its heterogeneity in chemical and physical properties, is an ideal test sites for evaluating potentialities/limitations of quantitative geochemical models of hydrothermal reactions. We used the EQ3/6 software package, version 7.2b, to model reaction of infiltrating waters (mixtures of meteoric water and seawater in variable proportions) with Ischia’s reservoir rocks (the Mount Ep…
ATR–FTIR Spectral Analysis and Soluble Components of PM10 And PM2.5 Particulate Matter over the Urban Area of Palermo (Italy) during Normal Days and …
2019
Several epidemiological studies have shown a close relationship between the mass of particulate matter (PM) and its effects on human health. This study reports the identification of inorganic and organic components by attenuated total reflectance-Fourier-transform infrared spectroscopy (ATR-FTIR) analysis in PM10 and PM2.5 filters collected from three air quality monitoring stations in the city of Palermo (Sicily, Italy) during non-Saharan dust events and Saharan events. It also provides information on the abundance and types of water-soluble species. ATR-FTIR analysis identified sulfate, ammonium, nitrate, and carbonate matter characterized by vibrational frequencies at 603, 615, 670, and …
Environmental and climatic controls of the clay mineralogy of Albian deposits in the Paris and Vocontian basins (France)
2020
18 pages; International audience; High-resolution clay mineral analyses were performed on lower and middle Albian deposits from the Paris and Vocontian basins in order to specify the weathering conditions that prevailed at that time. The clay mineral assemblages are composed of small proportions of chlorite and vermiculitic clays associated with abundant illite, R0 type illite-smectite mixed-layers (smectite) and kaolinite. Clay minerals originated from the physical alteration and chemical weathering of rocks and soils outcropping on the Variscan massifs bordering the studied areas. In the Paris Basin, the covariation of illite and kaolinite suggests the reworking of these latter minerals f…
Diagenesis of clay minerals and K-bentonites in Late Permian/Early Triassic sediments of the Sichuan Basin (Chaotian section, Central China).
2014
10 pages; International audience; Detailed clay mineralogical analyses were carried out on Late Permian/Early Triassic carbonate sediments exposed on the Chaotian section (Sichuan Basin, Central China). The clay assemblages are dominantly composed of illite in platform carbonates and clay seams, and illite-smectite mixed-layers (I/S) in tuff layers (K-bentonites) intercalated in the carbonate succession. Detrital and authigenic volcanogenic clay minerals have been partially replaced through illitisation processes during burial, raising questions about diagenetic effects. The precise determination of I/S occurring in K-bentonites shows that the sediments reached a temperature of about 180 °C…
Conjunctive use of spectral gamma-ray logs and clay mineralogy in defining late Jurassic-early Cretaceous palaeoclimate change (Dorset, U.K.).
2006
Abstract Detrital clay mineralogy is controlled by weathered source rock, climate, transport and deposition that in turn influence the spectral gamma-ray (SGR) response of resultant sediments. Whilst a palaeoclimate signal in clay mineralogy has been established in some ancient successions, the SGR response remains contentious, largely because the data sets have yet to be collected at the same or appropriate vertical scales to allow comparison. In addition, the influence of organic matter on SGR is not always considered. Here, we present clay mineralogical, total organic carbon (TOC) and SGR analyses from the late Jurassic and early Cretaceous of the Wessex Basin, a period of previously doc…
High-resolution clay mineralogy as a proxy for orbital tuning: example of the Hauterivian-Barremian transition in the Betic Cordillera (SE Spain).
2012
11 pages; International audience; The response of clay mineral assemblages to potential orbital forcing is tested in Mesozoic hemipelagic marl- limestone rhythmites of the Río Argos section (Betic Cordillera, Southeastern Spain). Along the section, marls are pervasively enriched in kaolinite and illite, whereas limestones are enriched in smectite-rich illite/smectite mixed-layers, suggesting that marl-limestone alternations are produced by cyclic high-frequency fluctuations of continental runoff. Spectral analyses show that clay mineral assemblages evolve accordingly to precession, obliquity and eccentricity cycles. Durations of ammonite zones are assessed at 535 kyr for the Late Hauterivia…
The Mid-Cenomanian Event in southeastern France: evidence from palaeontological and clay mineralogical data.
2013
16 pages; International audience; Reconstruction of main palaeoenvironmental conditions across the Mid-Cenomanian Event (MCE I) in the hemipelagic Tethyan section of Blieux (Southeast France, Vocontian Basin) is proposed. Quantitative analyses of calcareous nannofossil, ammonoid and clay mineral assemblages have been made and compared with respect to sea level changes and the carbon cycle perturbations. The nannofossil primary productivity, as recorded by nannofossil fluxes and relative abundances of meso-eutrophic taxa, is low just below and during the MCE Ia, then slightly increases in the interval including the MCE Ib. The clay assemblages mainly consist of illite/smectite mixed-layers w…
Late Jurassic palaeoclimatic change from clay mineralogy and gamma-ray spectrometry of the Kimmeridge Clay, Dorset, UK
2009
Abstract: The Late Jurassic was a time of increasing aridity in NW Europe. Here, a new clay mineral dataset is presented from a 600 m thick composite core through the Kimmeridge Clay Formation, southern England. Clay mineral assemblages comprise mainly illite and kaolinite, with minor randomly interstratified illite–smectite mixed-layer clays. SEM observations indicate that clay minerals are mainly detrital, except in silty strata of late Tithonian age, which contain abundant pore-filling kaolinite aggregates. Th/K ratios determined from gamma-ray spectrometry mirror palaeoclimatically significant variations in kaolinite/illite ratios, with notable exception where diagenetic kaolinite occur…
Specifications for carbonate content quantification in recent marine sediments using Rock-Eval pyrolysis
2019
11 pages; International audience; The amount of CaCO3 in sediments and/or sedimentary rocks is usually measured by calcimetry while the nature of the carbonates is determined by X-ray diffraction. Recently, a carbonate recognition method based on the results of Rock-Eval pyrolysis was proposed in 2014 by Pillot et al. [1]. Rock-Eval pyrolysis is also widely used for the characterization of recent sediments. However, later in 2015 Baudin et al. [2] noticed that some of the characteristics of recent sediments tended to produce different results from those of more classical Rock-Eval analyses, causing bias in interpretations.In this study, the thermal stability of fossil and recent marine carb…